Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 36, Pages 12641-12645Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602893
Keywords
arylation; C-H functionalisation; gold catalysis; heteroarenes; silicon
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Funding
- European Research Council under the European Union/ERC [340163]
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Tailoring of the pre-catalyst, the oxidant and the arylsilane enables the first room-temperature, gold-catalysed, innate C-H arylation of heteroarenes. Regioselectivity is consistently high and, in some cases, distinct from that reported with palladium catalysis. Tolerance to halides and boronic esters, in both the heteroarene and silane partners, provides orthogonality to Suzuki-Miyaura coupling.
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