Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 44, Pages 15659-15663Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603825
Keywords
allylic alcohols; X-ray absorption spectroscopy; isomerization; iridium; reaction mechanisms
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Funding
- Swedish Research Council (VR)
- Knut and Alice Wallenberg Foundation
- Swedish Governmental Agency for Innovation Systems (VINNOVA)
- Cambrex KA through the Berzelii Center EXSELENT
- VINNOVA through VINNMER
- Wenner-Gren Foundation
- MATsynCELL through the Runtgen-angstrom Cluster
- MAX IV Laboratory, Lund
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Remarkably simple Ir-III catalysts enable the isomerization of primary and sec-allylic alcohols under very mild reaction conditions. X-ray absorption spectroscopy (XAS) and mass spectrometry (MS) studies indicate that the catalysts, with the general formula [Cp*Ir-III], require a halide ligand for catalytic activity, but no additives or additional ligands are needed.
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