Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 38, Pages 13464-13468Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602257
Keywords
amino acid; decarboxylation; heterocycles; photoredox catalysis
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Funding
- European Research Council under the European Union/ERC [617044]
- European Research Council (ERC) [617044] Funding Source: European Research Council (ERC)
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A tin- and halide-free, visible-light photoredox-catalyzed Giese reaction was developed. Primary and secondary -amino radicals were generated readily from amino acids in the presence of catalytic amounts of an iridium photocatalyst. The reactivity of the -amino radicals has been evaluated for the functionalization of a variety of activated olefins.
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