Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 18, Pages 6218-6222Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201600229
Keywords
C-H activation; chelation-assisted; Cu-promoted; perfluoroalkylation; photocatalysis
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Funding
- National Basic Research Program of China [2015CB856500]
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A visible-light-induced and copper-promoted perfluoroalkylation of benzamides was successfully developed under the assistance of an 8-aminoquinoline directing group. It provides a straightforward method for the synthesis of ortho-perfluoroalkyl-substituted benzoic acid derivatives. The reaction employs a cheap organic dye eosin Y as the photoredox catalyst and is run under the irradiation of a 26 W fluorescent LED light bulb.
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