Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 8, Pages 1814-1819Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603851
Keywords
B(4)-H activation; o-carborane; palladium precursor complex; selectivity
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Funding
- National Science Foundation of China [21531002, 21374019]
- Changjiang Scholars and Innovative Research Team in University [IRT15R12]
- National Basic Research Program of China [2015CB856600]
- Shanghai Science and Technology Committee [13JC1400600]
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Palladium(II)-induced selective B(4)-H activation of an o-carboranylthioamide has been developed. A tetranuclear palladium(II) complex has been obtained in high yield with excellent regioselectivity. DFT calculations have con-firmed that the B(4)-borometalate is lower in energy than the corresponding B(3)-borometalate. The product proved to be a good precursor for target mononuclear or trinuclear B(4)-H activated complexes.
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