Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 23, Pages 7730-7733Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601006
Keywords
boranes; carbon dioxide; chemoselectivity; hydrosilylation; solvent effects
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Funding
- Deutsche Forschungsgemeinschaft through the International Research Training Group Selectivity in Chemo- and Biocatalysis
- Alexander von Humboldt Foundation
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Triphenylborane (BPh3) in highly polar, aprotic solvents catalyzes hydrosilylation of CO2 effectively under mild conditions to provide silyl formates with high chemoselectivity (> 95%) and without over-reduction. This system also promotes reductive hydrosilylation of tertiary amides as well as dehydrogenative coupling of silane with alcohols.
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