Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 35, Pages 12312-12315Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603071
Keywords
bonding; crystal structure; cyanides; cyanocarbon; radical ions
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Funding
- NSF MRSEC Grant [DMR-1121252 CFDA, 47.049]
- MINECO [MAT2014-54025-P]
- DGU [2014 SGR 1422]
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The reaction of 2,3,5,6-tetracyanopyridine (TCNPy) and Cr(C6H6)(2) forms diamagnetic sigma-[TCNPy](2)(2-) possessing a 1.572(3)angstrom intrafragment sp(3)-sp(3) bond. This is in contrast to the structurally related 1,2,4,5-tetracyanobenzene and 1,2,4,5-tetracyanopyrazine that form -dimer dianions possessing long, multicenter bonds.
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