Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 49, Pages 17542-17546Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603967
Keywords
C(cage)-C(sp(2)) formation; carboranyllithium; cross-coupling; direct C-arylation; palladium
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Funding
- National Natural Science Foundation of China [21403163, 21327011, 21376146]
- Natural Science Basic Research Plan in Shaanxi Province of China [2014JQ2062]
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A palladium-catalyzed direct C-arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides.
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