Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 15, Pages 3502-3541Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602124
Keywords
boron; diene; linchpin reagents; natural products; polyene compounds
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Funding
- National Science Centre (Poland) [UMO-2011/02/A/ST5/00472]
- HOMING grant of the Foundation for Polish Science [PLUS/2012-5/14]
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In the syntheses developed to access naturally occurring compounds, especially bioactive substances, boron-functionalized dienes (also linchpin reagents) are used as key reagents. Structurally unique dienes are found in nature, and play important biological and chemical roles. Recently, linchpin moieties have been proved as useful substrates for a variety of highly functionalized chemical transformations. The products of these processes are potentially of some use for the syntheses of an important class of natural products showing a wide range of biological activities. This review describes progress in the synthesis of borylsubstituted buta-1,3-dienes as well as their application in organic chemistry.
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