Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 12, Pages 4030-4035Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201504844
Keywords
alkenes; arylation; hypervalent iodine; oxidation; rearrangement
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Funding
- EPSRC [EP/J00569X/1]
- EU [621956]
- School of Chemistry, Cardiff University
- EPSRC [EP/J00569X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/J00569X/1] Funding Source: researchfish
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A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched -arylated ketones without the use of transition metals from readily accessible alkenes.
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