Journal
ACS CATALYSIS
Volume 10, Issue 8, Pages 4786-4790Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c00610
Keywords
C-H functionalization; asymmetric photocatalysis; hydrogen atom transfer; enantioselective protonation; chiral phosphoric acid
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Funding
- NSFC [21602214]
- University of Science and Technology of China
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In the presence of tetrabutylammonium decatungstate and chiral Spiro phosphoric acid, a light-mediated asymmetric C-H functionalization of unactivated hydrocarbons with exocyclic enones has been established. A wide range of cycloalkanes, benzylic, and allylic hydrocarbons are tolerated. This protocol proceeds via a hydrogen atom transfer/radical addition/hydrogen abstraction/enantioselective protonation relay process.
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