Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 16, Pages 5509-5513Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201600526
Keywords
adsorption; host-guest systems; liquid chromatography; metal-organic frameworks; microporous materials
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Funding
- US Department of Energy [DE-SC0004888]
- NSF [CHE-0840456]
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The design, synthesis, and properties of the new microporous coordination polymer UMCM-310 are described. The unique electronic character of the perylene-based linker enables selective interaction with electron-poor aromatics leading to efficient separation of nitroaromatics. UMCM-310 possesses high surface area and large pore size and thus permits the separation of large organic molecules based on adsorption rather than size exclusion.
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