Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 47, Pages 16733-16748Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603438
Keywords
difluoromethylation; difluoromethylthiolation; fluorine; sulfur; synthetic methods
Categories
Funding
- INSA Rouen, Rouen University
- CNRS
- EFRD
- Labex SynOrg [ANR-11-LABX-0029]
- Region Haute-Normandie (Crunch Network)
- China Scholarship Council (CSC)
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In recent years, much interest has been paid to difluoromethylthiolated molecules as the SCF2 moiety is a key motif in drug and agrochemical research. Consequently, the development of versatile strategies for the selective synthesis of SCF2H- and SCF(2)FG-containing molecules (FG= functional group) has attracted a lot of attention and in-spired the scientific community to design new tools. This Minireview highlights the major progress made in this field. Particularly, methodologies developed for the difluoromethylation of sulfur-containing molecules and the direct construction of C-SCF2 bonds in various classes of compounds are showcased and discussed.
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