Synthesis of Hierarchically Porous Sandwich-Like Carbon Materials for High-Performance Supercapacitors

For the first time, hierarchically porous carbon materials with a sandwich-like structure are synthesized through a facile and efficient tri-template approach. The hierarchically porous microstructures consist of abundant macropores and numerous micropores embedded into the crosslinked mesoporous walls. As a result, the obtained carbon material with a unique sandwich-like structure has a relatively high specific surface (1235 m(2)g(-1)), large pore volume (1.30 cm(3)g(-1)), and appropriate pore size distribution. These merits lead to a comparably high specific capacitance of 274.8 Fg(-1) at 0.2 Ag-1 and satisfying rate performance (87.7% retention from 1 to 20 Ag-1). More importantly, the symmetric supercapacitor with two identical as-prepared carbon samples shows a superior energy density of 18.47 Whkg(-1) at a power density of 179.9 Wkg(-1). The asymmetric supercapacitor based on as-obtained carbon sample and its composite with manganese dioxide (MnO2) can reach up to an energy density of 25.93 Whkg(-1) at a power density of 199.9 Wkg(-1). Therefore, these unique carbon material open a promising prospect for future development and utilization in the field of energy storage.