Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 6, Pages 2100-2107Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201504305
Keywords
aluminium; chromium; cyclic carbonates; epoxides; homogeneous catalysis; salphen ligands
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Funding
- European Union [309497]
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Chromium and aluminium salphen complexes have been found to display remarkable catalytic activity in the synthesis of cyclic carbonates from a range of epoxides and carbon dioxide. The Al(salphen) complex is more reactive towards terminal epoxides at ambient temperature and pressure, whereas the Cr(salphen) complex exhibits higher catalytic activity towards more challenging internal epoxides at elevated temperature and pressure.
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