Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 26, Pages 8809-8813Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601642
Keywords
carbon dioxide reduction; gallium nitride; photocathodes; photoelectrocatalysis; solar fuel
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Climate Change and Emissions Management Corporation (CCEMC)
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A gallium nitride nanowire/silicon solar cell photocathode for the photoreduction of carbon dioxide (CO2) is demonstrated. Such a monolithically integrated nanowire/solar cell photocathode offers several unique advantages, including the absorption of a large part of the solar spectrum and highly efficient carrier extraction. With the incorporation of copper as the co-catalyst, the devices exhibit a Faradaic efficiency of about 19% for the 8e(-) photoreduction to CH4 at -1.4 V vs Ag/AgCl, a value that is more than thirty times higher than that for the 2e(-) reduced CO (ca. 0.6%).
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