Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 47, Pages 16786-16789Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604504
Keywords
C-H borylation; C-O bond activation; decarbonylative cross-coupling; esters; nickel
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Funding
- China Scholarship Council
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A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.
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