Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 30, Pages 10330-10335Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602039
Keywords
cage-to-cage transformation; palladium; reorganization; self-assembly; subcomponents
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Funding
- SERB, Department of Science and Technology, Government of India [SB/S1/IC-05/2014]
- UGC, India
- CSIR, India
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A series of Pd2L4-type binuclear self-assembled coordination cages (1-4), where L stands for a nonchelating bidentate ligand, were prepared. The strategies adopted for the synthesis of the cages were: combination of Pd-II with 1)a selected ligand or 2)subcomponents of the ligand. Highly efficient cage-to-cage transformation reactions are demonstrated by suitable covalent modification (from 1 to 2 or 3 or 4) or ligand-exchange reactions (from 1 to 2 or 3 or 4; from 2 to 3 or 4). Thus, new cascade transformations (from 1 to 2 to 3; from 1 to 2 to 4) are achieved beautifully.
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