Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 32, Pages 11283-11290Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201600705
Keywords
adsorption; chemical stability; fluorinated metal clusters; hydrophobicity; metal-organic frameworks
Categories
Funding
- 973 key program of the Chinese Ministry of Science and Technology (MOST) [2012CB821705]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Chinese Academy of Sciences [KJCX2-YW-319, KJCX2-EW-H01]
- National Natural Science Foundation of China [21373221, 21521061, 91122027, 51172232, 21403236]
- Natural Science Foundation of Fujian Province [2012J06006, 2014J05026, 2006L2005]
- Postdoctoral Scientific Research Foundation of Fuzhou University [0180-601372]
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Hydrophobic metal-organic frameworks (MOFs) not only have high water stability, but also exhibit high adsorption capacity towards organic molecules, in particular hydrocarbons. Herein we report a rare metal fluoride organic framework MFOF-1 with high hydrophobicity, which is constructed from unprecedented fluoride- and sulfate-bridged cubane-type tetranuclear cobalt clusters. MFOF-1 consists of three types of polyhedral cages with face-sharing configurations, and possesses a novel (3,9)-connected 3D+3D -> 3D self-interpenetrating array or the rare pyr topology. MFOF-1 shows high thermal stability and high stability in water and even acid/base aqueous solutions, and exhibits rather high H-2 and CO2 storage capacities at ambient pressure. Remarkably, MFOF-1 shows little adsorption of water but considerably high uptakes of methanol, n-hexane, cyclohexane, and benzene, and exhibits a certain degree of adsorption selectivity of benzene over cyclohexane.
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