Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 19, Pages 6524-6527Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201600682
Keywords
carbon dioxide; C-C activation; C-H activation; copper; synthetic method
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Funding
- MEXT [22105005, 15H05756]
- ACT-C Program of the JST
- Yazaki Memorial Foundation for Science and Technology
- Grants-in-Aid for Scientific Research [14J03286, 15H05756, 22105005] Funding Source: KAKEN
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A photo-induced carboxylation reaction of allylic C-H bonds of simple alkenes with CO2 is prompted by means of a ketone and a copper complex. The unique carboxylation reaction proceeds through a sequence of an endergonic photoreaction of ketones with alkenes forming homoallyl alcohol intermediates and a thermal copper-catalyzed allyl transfer reaction from the homoallyl alcohols to CO2 through C-C bond cleavage.
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