Journal
SYNTHESIS-STUTTGART
Volume 52, Issue 16, Pages 2311-2329Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707115
Keywords
triarylmethane; preparation; 9-arylxanthenones; 9-arylfluorenes; aryloxepines
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Funding
- Natural Science Foundation of Zhejiang Province [LQ18B020001]
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Triarylmethanes are important molecules in organic chemistry. This review discusses advances in their synthesis summarized in five categories according to the starting materials: (1) benzyl reagents with different leaving groups, such as benzyl alcohols, ethers, esters, phosphates, sulfones, thioethers, sulfonamide, 1,3-dicarbonyls, and ammonium salts; (2) reactions via para- or ortho-quinone methides; (3) arylation of benzyl halides; (4) C-H activation of methylenes; and (5) reactions of aldehydes or N-tosylhydrazones. Triarylmethane derivatives such as 9-arylxanthenones, 9-arylfluorenes, and aryloxepines are also discussed. 1 Introduction 2 Benzyl Reagents with Leaving Groups 3 Quinone Methide Mediated Reactions 4 Arylation of Benzyl Halides 5 C-H Activation of Methylene 6 Reactions of Carbonyl Compounds 7 Conclusions
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