4.4 Article

A Finding on the Direct Regioselective Cyanation of BODIPY

Journal

SYNLETT
Volume 31, Issue 11, Pages 1064-1066

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690888

Keywords

BODIPY; cyanation; nucleophilic aromatic substitution; hydrogen substitution; regioselective substitution

Funding

  1. Scientific and Technological Research Council of Turkey [215Z044]
  2. Hacettepe University Scientific Research Projects Coordination Unit [FBA-2015-5633]

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The first example of direct alpha-cyanation of a BODIPY core has been achieved on 3-(methoxycarbonyl)ethenyl BODIPY. The structure of alpha-cyanated BODIPY was confirmed by X-ray analysis. Further cyanation took place on the meso-carbon of BODIPY.

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