Journal
SYNLETT
Volume 31, Issue 12, Pages 1201-1204Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707862
Keywords
ring enlargement; cyclic 1,3-diketone; cyclic 1,5-diketone; mono-vinylation; potassium tert-butoxide
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Funding
- Japan Society for the Promotion of Science (JSPS KAKENHI) [19K05473]
- Kanazawa University SAKIGAKE project
- Grants-in-Aid for Scientific Research [19K05473] Funding Source: KAKEN
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3-Hydroxy-3-vinylcycloalkanones, which were prepared from the corresponding cyclic 1,3-diketories by mono-vinylation, were rearranged to two-carbon ring enlarged cyclic 1,5-diketones by treatment with a catalytic amount of potassium tert-butoxide.
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