Journal
CHEMISTRY OF MATERIALS
Volume 28, Issue 19, Pages 6968-6974Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.6b02653
Keywords
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Funding
- National Natural Science Foundation of China [51321091, 51227002, 51272129]
- Program of Introducing Talents of Disciplines to Universities in China (111 program) [b06015]
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The hybrid perovskites with special optoelectronic properties have attracted more attention to the scientific and industrial applications. However, because of the toxicity and instability of lead complexes, there is interest in finding a nontoxic substitute for the lead in the halides perovskites and solving the ambiguous crystal structures and phase transition of NH(CH3)(3)SnX3 (X = Cl, Br). Here, we report the bulk crystal growths and different crystal morphologies of orthorhombic hybrid perovskites NH(CH3)(3)SnX3 (X = Cl, Br) in an ambient atmosphere by bottom-seeded solution growth (BSSG) method. More importantly, detailed structural determination and refinements, phase transition, band gap, band structure calculations, nonlinear optical (NLO) properties, XPS, thermal properties, and stability of NH(CH3)(3)SnX3 (X = Cl, Br) single crystals are demonstrated. NH(CH3)(3)SnCl3 single crystal undergoes reversible structural transformation from orthorhombic space group Cmc2(1) (no. 36) to monoclinic space group Cc (no. 9) and NH(CH3)(3)SnBr3 belongs to the orthorhombic space group Pna2(1) (no. 33) by DSC, single-crystal X-ray diffraction and temperature-dependent SHG measurements, which clarify the former results. These results should pave the way for further studies of these materials in optoelectronics.
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