Journal
CHEMISTRY OF MATERIALS
Volume 28, Issue 10, Pages 3515-3524Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.6b01303
Keywords
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Funding
- National Natural Science Foundation of China [11574312, 51472242, 11304312]
- Natural Science Foundation of Fujian Province [2015J01032]
- Fujian Provincial Key Project of Science Technology [2015H0051]
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Owing to its low cost and admirable luminescent characteristics for use in warm white-light-emitting diode (w-LED) applications, the non-rare-earth Mn4+-activated red phosphor has emerged as a potent competitor of commercial Eu2+-doped nitrides in recent years. In this work, the novel red-emitting phosphor BaMgAl(10-2)xO(17):xMn(4+),xMg(2+) is successfully synthesized, which exhibits bright and narrow-band luminescence peaking at 660 nm with a full width at half-maximum of merely similar to 30 nm upon blue light excitation. The unique structural feature of BMA, i.e., alternating arrangements of Mn4+-doped (MgAlO16)-O-10/undoped BaO layers in the z direction and Mn(4+-)doped [AlO6]/undoped [AlO4] groups in the x-y plane, favors efficient Mn4+ luminescence by reducing nonradiative energy loss channels. Unlike previously reported hosts, BMA accommodates Mg2+ in the lattice without destabilizing the crystal structure. Remarkably, partitioning Mg2+ in the host not only greatly enhances Mn4+ luminescence by 1.84-fold but also retards the concentration quenching effect induced by Mn4+ dipole-dipole interactions owing to the reduced number of Mn4+-Mn4+-O2- pairs. Spectroscopy demonstrates that the luminescence of optimized BMA:0.02Mn(4+),0.02Mg(2+) exhibits a high color purity of 98.3%, good color stability against heat, and excellent resistance to thermal impact. When incorporating BMA:0.02Mn(4+),0.02Mg(2+) and YAG:Ce3+ phosphors into an oxide glass matrix at various ratios and then coupling the phosphor-in-glass color converters using a blue chip, the chromaticity parameters of the fabricated w-LED are well-tuned, with the correlated color temperature decreasing from 6608 to 3622 K and the color rendering index increasing from 68.4 to 86.0, meeting the requirements for in-door lighting use.
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