Journal
CHEMISTRY OF HETEROCYCLIC COMPOUNDS
Volume 52, Issue 6, Pages 402-408Publisher
SPRINGER
DOI: 10.1007/s10593-016-1901-z
Keywords
1,2,4-triazole; triazolylacetic acid; acylation; decarboxylation; intramolecular condensation
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A range of 1,2,4-triazolylacetic acids and their derivatives with various substituents at the triazole ring position 3 have been synthesized. The properties of the obtained compounds were studied, showing that: 1) triazolylacetic esters are strong acylating agents; 2) all the obtained triazolylacetic acids underwent decarboxylation when heated to the melting point; 3) the CH2 group in the acetyl moiety can react as methylene component in condensation reactions.
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