Journal
CHEMISTRY LETTERS
Volume 45, Issue 1, Pages 45-47Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.150807
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Funding
- MEXT [15H05799]
- Grants-in-Aid for Scientific Research [15H05799] Funding Source: KAKEN
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Nickel-catalyzed hydrogenolysis of arenols has been developed through the use of hydrosilane as a reductant. Sterically demanding N-heterocyclic carbene (NHC) ligands are crucial for the reaction. The present protocol allows selective cleavage of Ar-O bonds of arenols over aryl and benzyl ethers.
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