4.5 Article

Synthesis, characterization and catalytic application of tributyl(carboxymethyl)phosphonium bromotrichloroferrate as a new magnetic ionic liquid for the preparation of 2,3-dihydroquinazolin-4(1H)-ones and 4H-pyrimidobenzothiazoles

Journal

RESEARCH ON CHEMICAL INTERMEDIATES
Volume 46, Issue 8, Pages 3945-3960

Publisher

SPRINGER
DOI: 10.1007/s11164-020-04183-y

Keywords

2; 3-Dihydroquinazolin-4(1H)-one; Magnetic ionic liquid; Multicomponent reaction; Phosphonium ionic liquid; 4H-Pyrimidobenzothiazole

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In this paper, tributyl(carboxymethyl)phosphonium bromotrichloroferrate as a new magnetic ionic liquid bearing acetic acid tags was synthesized and characterized by several methods including Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA) and derivative thermogravimetry analysis (DTG). The prepared magnetic ionic liquid was applied as catalyst for synthesis of 2,3-dihydroquinazolin-4(1H)-ones and 4H-pyrimidobenzothiazole derivatives under solvent free conditions. Graphic abstract Novel magnetic ionic liquid show high catalytic performance for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones and 4H-pyrimidobenzothiazole derivatives.

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