Journal
CHEMISTRY LETTERS
Volume 45, Issue 4, Pages 415-417Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.160022
Keywords
Thiophene-based polymer; Brush-shaped pi-conjugated polymer; Living cationic polymerization
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Funding
- Japan Society for the Promotion of Science (JSPS) [26820314]
- Cooperative Research Program of Network Joint Research Center for Materials and Devices
- Foundation for the Promotion of Ion Engineering
- Kyoto Technoscience Center
- Grants-in-Aid for Scientific Research [26820314] Funding Source: KAKEN
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For the synthesis of brush-shaped pi-conjugated polymers having thiophene-based backbones, novel thiophene-end-capped poly(vinyl ether) macromonomers (Th-PMEEVE) were synthesized by living cationic polymerization with a new thiophene-appended initiator. It was found that polycondensation reactions of these macromonomer and 4,7-dibromo-2,1,3-benzothiadiazole (BTDA) via direct arylation reaction afforded the target brush shaped pi-conjugated polymers having a poly(thiophene-alt-BTDA) backbone [poly(Th-PMEEVE-alt-BTDA)].
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