Journal
POLYMER ENGINEERING AND SCIENCE
Volume 60, Issue 7, Pages 1430-1436Publisher
WILEY
DOI: 10.1002/pen.25390
Keywords
biodegradable polymeric stents; differential scanning calorimetry; gel permeation chromatography; mechanical properties; spherical nanoindentation
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The next-generation bioresorbable polymeric stents are undergoing continual research and development, especially how to control and optimize their degradation behaviors. The aim of this paper is to study the properties of a poly(l-lactide) (PLLA) tube over accelerated degradation in vitro. Spherical nanoindentation was particularly adopted to measure the mechanical properties of PLLA tube; while differential scanning calorimetry and gel permeation chromatography were used for crystallinity and molecular weight measurements. Overall, the material degradation was captured by the local stress-strain response obtained with spherical nanoindentation, and further confirmed with chemical analyses. The results are particularly useful for development of bioresorbable polymeric stents with improved performance.
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