Journal
PETROLEUM CHEMISTRY
Volume 60, Issue 3, Pages 291-297Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544120030056
Keywords
titanium; zirconium; and vanadium compounds; salen ligands; polymerization of ethylene; ultrahigh-molecular-weight polyethylene; olefins; organoaluminum compounds
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Funding
- Russian Science Foundation [18-13-00375]
- Russian Foundation for Basic Research [19-03-00312]
- Russian Science Foundation [18-13-00375] Funding Source: Russian Science Foundation
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Coordination compounds of titanium(IV), zirconium(IV), and vanadium(V) with chiral salen ligands have been obtained and characterized, and their catalytic activity in the polymerization reaction of ethylene has been studied. It has been shown that in the presence of polymethylaluminoxane as a cocatalyst, the activity of the titanium-containing catalyst system reaches 944 kgPE mol(Ti)(-1) h(-1) and leads to the preparation of ultrahigh-molecular-weight polyethylene.
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