Journal
CHEMICAL SOCIETY REVIEWS
Volume 45, Issue 8, Pages 2044-2056Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cs00655d
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Funding
- National Science Foundation of China [21272087, 21472058, 21232003]
- Youth Chen-Guang Project of Wuhan [2015070404010180]
- College's Basic Research and Operation of MOE [CCNU15A02009]
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Radicals are an important class of versatile and highly reactive species. Compared with the wide applications of various C-centred radicals, however, the N-radical species including N-centred radicals and radical ions remain largely unexplored due to the lack of convenient methods for their generation. In recent years, visible light photoredox catalysis has emerged as a powerful platform for the generation of various N-radical species and methodology development towards the synthesis of diverse N-containing compounds. In this tutorial review, we highlight recent advances in this rapidly developing area with particular emphases put on the working models and new reaction design.
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