Journal
CHEMICAL SOCIETY REVIEWS
Volume 45, Issue 3, Pages 506-516Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cs00821b
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Funding
- Shanghai Pujiang Program [14PJ1403100]
- National Natural Science Foundation of China [21572065, 21425205, 21372084]
- 973 Programs [2015CB856600]
- Program of Eastern Scholar at Shanghai Institutions of Higher Learning, Changjiang Scholars and Innovative Research Team in University (PCSIRT)
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Metal carbenes, generated from the decomposition of diazo compounds by transition-metals, have a broad range of applications in organic synthesis. The progress of organic transformation via transition metal (such as Rh, Cu, Fe, Ag) carbenes has been well summarized in a few excellent reviews. This review will summarize gold-catalyzed transformations of alpha-diazocarbonyl compounds by highlighting the specificity and applicability of these diverse transformations such as X-H insertion, C-H functionalization, cyclopropanation, cycloaddition, and coupling reactions. In order to understand these reactions, the mechanistic rationale for selected examples is also provided.
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