Journal
CHEMICAL SOCIETY REVIEWS
Volume 45, Issue 8, Pages 2291-2307Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cs00886g
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Funding
- Ministerio de Economia y Competitividad [CTQ2010-17436, CTQ2013-40855-R]
- Gobierno de Aragon - Fondo Social Europeo (research group E40)
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This review describes available methods for the preparation of alpha-aminoboronic acids in their racemic or in their enantiopure form. Both, highly stereoselective syntheses and asymmetric procedures leading to the stereocontrolled generation of alpha-aminoboronic acid derivatives are included. The preparation of acyclic, carbocyclic and azacyclic alpha-aminoboronic acid derivatives is covered. Within each section, the different synthetic approaches have been classified according to the key bond which is formed to complete the alpha-aminoboronic acid skeleton.
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