Journal
ORGANOMETALLICS
Volume 39, Issue 11, Pages 2130-2134Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.0c00187
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Funding
- JSPS [JP17H01201, JP15H05798, JP18K19093, JP19K23645]
- CREST, JST [JPMJCR1541]
- MEXT
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Ruthenium-catalyzed propargylic reduction of propargylic alcohols bearing a terminal alkyne moiety is accomplished by using Hantzsch ester as a nucleophilic hydride source. A variety of secondary and tertiary propargylic alcohols are reduced to the corresponding propargylic reduced products such as 1-alkynes in excellent yields. Some mechanistic studies indicate that ruthenium-allenylidene complexes may work as key reactive intermediates.
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