4.5 Article

Cobalt-Catalyzed Ligand-Controlled Divergent Regioselective Reactions of 1,6-Enynes with Thiols

Journal

ORGANOMETALLICS
Volume 39, Issue 11, Pages 2037-2042

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.0c00179

Keywords

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Funding

  1. National Natural Science Foundation of China [21961045]
  2. Applied Basic Research Project of Yunnan Province [2017FA004, 2018FB021]
  3. Department of Education of Yunnan Province [2019J0683]
  4. Yunnan Provincial Key Laboratory Construction Plan Funding of Universities
  5. Yunnan Provincial Engineering Research Center Construction Plan Funding of Universities

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An efficient cobalt-catalyzed method for the synthesis of carbocyclic organosulfur compounds from 1,6-enynes and thiols has been developed. The significance of this methodology is the ability to give three different cyclization products depending on the ligands used. The products were obtained in moderate to good yields with broad substrate scope.

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