Journal
ORGANOMETALLICS
Volume 39, Issue 11, Pages 2116-2124Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.0c00176
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Funding
- EPSRC Centre for Doctoral Training for Sustainable Chemistry [EP/L015633/1]
- University of Nottingham Green Chemicals Beacon
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We report a fluorine transfer reaction in which fluorine from a perfluorinated ligand undergoes C-F bond activation and transfers to an electrophile, resulting in the formation of a new fluorinated product and dimerization of the monodefluorinated complex. Treatment of [(eta(5),kappa C-2-C5Me4CH2C6F5CH2NC3H2NMe)-RhCl] with the organic electrophile, toluoyl chloride, resulted in the formation of a rhodium(III) metallocycle via C-F bond activation assisted defluorinative coupling. Fission of the C-F bond liberated nucleophilic fluoride, which converted acyl chloride to acyl fluoride. The overall reaction was monitored using a multivariate analysis approach in real time.
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