Journal
ORGANIC LETTERS
Volume 22, Issue 11, Pages 4418-4423Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01424
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Funding
- National Key R&D Program of China [2016YFA0202900]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Science and Technology Commission of Shanghai Municipality [18XD1405000]
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A nickel-catalyzed homo- and cross-coupling of allylic alcohols to 1,5-dienes in the presence of B(2)pin(2) with excellent regioselectivity has been developed. Mechanistic studies indicate that the reaction proceeds via sequential nickel-catalyzed borylation of allyl alcohols followed by cross-coupling of the resulting allyl boronates with allyl alcohols. The method was effectively applied to nickel-catalyzed allylation of aldehydes using allylic alcohols directly.
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