Journal
ORGANIC LETTERS
Volume 22, Issue 10, Pages 3993-3999Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01317
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Funding
- National Natural Science Foundation of China [21602015, 21703195]
- Jilin Provincial 13th Five Year Plan Science and Technology Project [JJKH20181022KJ]
- Talent Development Fund of Jilin Province
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A ring-opening/alkyne - carbonyl metathesis sequence of alkyne-tethered cyclobutanones catalyzed by AgSbF6 is realized for the first time to furnish multisubstituted naphthyl ketones under mild conditions. A range of substrates decorated with various substituents at different positions were all well accommodated. Preliminary mechanistic studies show that silver salt acted as a Lewis acid to facilitate both C-C cleavage of the cyclobutanone moiety and the subsequent metathesis between C=O and C C bonds.
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