Journal
ORGANIC LETTERS
Volume 22, Issue 10, Pages 3804-3809Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01050
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Funding
- Ministry of Science and Technology of China [2017YFA0206903]
- National Natural Science Foundation of China [21861132004]
- Strategic Priority Research Program of the Chinese Academy of Science [XDB17000000]
- Key Research Program of Frontier Sciences of the Chinese Academy of Science [QYZDY-SSW-JSC029]
- K. C. Wong Education Foundation
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Direct C-S bond coupling is an attractive way to construct aryl sulfur ether, a building block for a variety of biological active molecules. Herein, we disclose an effective model for regioselective thiolation of the aromatic C-H bond by thiol activation instead of arene activation. Strikingly, this method has been applied into anisole derivatives that are not available in the arene activation approach to forge a single thioether isomer with high reactivity.
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