Journal
ORGANIC LETTERS
Volume 22, Issue 11, Pages 4261-4265Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01294
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Funding
- National Natural Science Foundation of China [21961045, 21572198]
- Applied Basic Research Project of Yunnan Province [2017FA004, 2018FB021]
- Yunnan Provincial Key Laboratory Construction Plan Funding of Universities
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A facile and cost-effective method for the preparation of fluoroalkylated compounds has been described by the direct photoexcitation of halofluoroalkanes with blue light absorptivity, enabling the difluoroalkylation of aryl ketones. The methodology has provided an efficient, mild, and catalyst-free synthetic method for quaternary difluoroalkylated arenes and tetrasubstituted monofluoroalkenes.
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