Journal
ORGANIC LETTERS
Volume 22, Issue 11, Pages 4517-4522Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01527
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Funding
- Ecole Polytechnique Federale de Lausanne (EPFL)
- Swiss National Science Foundation [200021_165788]
- Swiss National Science Foundation (SNF) [200021_165788] Funding Source: Swiss National Science Foundation (SNF)
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Donor-acceptor cyclopropanes substituted with 3,3-dialkyltriazenyl groups are described herein. The strong electron-donating character of the triazene renders the cyclopropanes highly reactive, allowing for catalyst-free ring-opening reactions with methanol and tetracyanoethylene under mild conditions. The triazene-substituted cyclopropanes could also be used as substrates in Lewis acid catalyzed (3 + 2) annulations with silyl enol ethers.
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