Journal
ORGANIC LETTERS
Volume 22, Issue 8, Pages 2950-2955Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00679
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Funding
- NSFC [21801029]
- Graduate Scientific Research and Innovation Foundation of Chongqing [CYS18046]
- Natural Science Foundation of Chongqing [cstc2019jcyjmsxmX0048]
- Chongqing Postdoctoral Science Foundation [cstc2019jcyj-bshx0057]
- Sichuan Key Laboratory of Medical Imaging (North Sichuan Medical College) [SKLMI201901]
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Herein, we report the iron-catalyzed borylation of aryl ethers and aryl amines via deavage of C-O and C-N bonds. This protocol does not require the use of Grignard reagents and displays a broad substrate scope, which allows the late-stage borylation. It also provides facile access to multisubstituted arenes through C-H fiinctionalization using 2-pyridyloxy as the directing group.
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