Journal
ORGANIC LETTERS
Volume 22, Issue 8, Pages 3018-3022Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00788
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Funding
- National Research Foundation of Korea (NRF) - Korean government (MSICT) [NRF-2015R1A5A1008958, NRF-2019R1A2C2089953]
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The photoredox chloroacylation of alkenes has been developed as a substitute for the Friedel-Crafts acylation of alkenes to beta-chloroketones. The direct generation of acyl radical species from acid chlorides under the photoredox conditions allows the formation of beta-chloroketones without dehydrochlorination with the help of KHCO3. The synthetic utility of the current method is demonstrated in the one-pot synthesis of dihydroisoxazole, dihydropyrazole, and dihydropyrimidine-2-thione in 1 mmol scale.
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