Journal
ORGANIC LETTERS
Volume 22, Issue 7, Pages 2822-2827Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00822
Keywords
-
Categories
Funding
- MEXT
- JSPS KAKENHI [JP19K15570]
- Tobe Maki Foundation
- Tokyo Ohka Foundation for The Promotion of Science and Technology
- Fukuoka Naohiko Foundation
Ask authors/readers for more resources
We report the photocatalytic C-H amination of aromatics overcoming redox potential limitations. Radical cations of aromatic compounds are generated photocatalytically using Ru(phen)(3)(PF6)(2), which has a reduction potential at a high oxidation state (E-red(Ru-III/Ru-II) = +1.37 V vs SCE) lower than the oxidation potentials of aromatic substrates (E-ox = +1.65 to +2.27 V vs SCE). The radical cations are trapped with pyridine to give N-arylpyridinium ions, which were converted to aromatic amines.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
