Journal
ORGANIC LETTERS
Volume 22, Issue 7, Pages 2811-2815Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00796
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Funding
- NSFC [21532001]
- International Joint Research Centre for Green Catalysis and Synthesis, Gansu Provincial Sci. & Tech. Department [2016B01017]
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A novel catalytic tautomeric transformation of a beta-enaminophosphoryl and 2-aza-Cope rearrangement sequence has been successfully applied to the one-pot synthesis of beta-aminophosphonates with high efficiency and good tolerance. In this tandem reaction, Bi(OTf)(3) exhibits unique activities and promotes both of enamine-imine tautomerism and 2-aza-Cope rearrangement.
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