Journal
ORGANIC LETTERS
Volume 22, Issue 9, Pages 3566-3569Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01013
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Funding
- Ministry of Education, Science, Sports, and Culture, Japan [17H02740]
- Canon Foundation
- Grants-in-Aid for Scientific Research [17H02740] Funding Source: KAKEN
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Chloroformates are key reagents for synthesizing carbonates and carbamates. The present study reports a novel photo-on-demand in situ synthesis of chloroformates with a CHCl3 solution containing a primary alkyl alcohol. It further allowed the one-pot synthesis of carbonates and carbamates through subsequent addition of alcohols or amines, respectively.
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