Journal
ORGANIC LETTERS
Volume 22, Issue 8, Pages 2878-2882Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00451
Keywords
-
Categories
Funding
- SERB, New-Delhi [EMR/2016/006358]
- Indian Institute of Science, R L Fine Chem, Bangalore
- SYNMR Chemicals Pvt. Ltd., Bangalore
- CSIR, New-Delhi
Ask authors/readers for more resources
Rh(III)-catalyzed C-H activation and cyclization of sulfoxonium ylide with acrylates leads to an efficient synthesis of indanone derivatives. The reaction proceeds under mild and external metal-oxidant-free conditions. The sulfoxonium ylide acts as a traceless directing group as well as an internal oxidant. (4 + 1) Annulation after C-H activation leads to the formation of a carbocyclic ring, and the byproduct obtained is DMSO, which can be easily separated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available