4.8 Article

Geometrically Selective Denitrative Trifluoromethylthiolation of β-Nitrostyrenes with AgSCF3 for (E)-Vinyl Trifluoromethyl Thioethers

Journal

ORGANIC LETTERS
Volume 22, Issue 12, Pages 4868-4872

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01714

Keywords

-

Funding

  1. National Natural Science Foundation of China [21562041, 21971089]
  2. Fundamental Research Funds for the Central Universities

Ask authors/readers for more resources

An efficient copper(II)-promoted denitrative trifluoromethylthiolation under mild reaction conditions has been developed for vinyl trifluoromethyl thioethers to construct C-vinyl-SCF3 bonds with stable AgSCF3 as a source of the trifluoromethylthio. This reaction system tolerates a broad range of functional groups to commendably achieve a high product yield and excellent stereoselectivity of E/Z.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available