Journal
ORGANIC LETTERS
Volume 22, Issue 12, Pages 4868-4872Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01714
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Funding
- National Natural Science Foundation of China [21562041, 21971089]
- Fundamental Research Funds for the Central Universities
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An efficient copper(II)-promoted denitrative trifluoromethylthiolation under mild reaction conditions has been developed for vinyl trifluoromethyl thioethers to construct C-vinyl-SCF3 bonds with stable AgSCF3 as a source of the trifluoromethylthio. This reaction system tolerates a broad range of functional groups to commendably achieve a high product yield and excellent stereoselectivity of E/Z.
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