Journal
CHEMICAL REVIEWS
Volume 116, Issue 17, Pages 10035-10074Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.6b00018
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- NIH [GM09888]
- Sloan Foundation
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The interaction between an electronically excited photocatalyst and an organic molecule can result in the genertion of a diverse array of reactive intermediates that can be manipulated in a variety of ways to result in synthetically useful bond constructions. This Review summarizes dual-catalyst strategies that have been applied to synthetic photochemistry. Mechanistically distinct modes of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer, and energy transfer. We focus upon the cooperative interactions of photocatalysts with redox mediators, Lewis and Bronsted acids, organocatalysts, enzymes, and transition metal complexes.
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